화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 가을 (11/02 ~ 11/04, 경원대학교)
권호 15권 2호
발표분야 고분자
제목 Chemical anchoring of PHEMA on SiO2 nanoparticles by surface thiol-lactam initiated radical polymerization
초록 In this discussion, we would like to discuss a facile method to synthesize a hybrid of poly(2-hydroxyethylmethacrylate), a polymer widely employed for biomedical applications, and SiO2 nanoparticles, exhibiting a well-known bioactivity, by employing the thiol-lactam initiated radical polymerization (TLIRP) upon grafting from strategy. The chemical immobilization of PHEMA onto the surface of SiO2 nanoparticles was confirmed by FT-IR, XPS, EDX and XRD analyses. The morphological feature of hybrid nanocomposites was investigated by FE-SEM and TEM. A moderate degree of functionalization of SiO2 nanoparticles by PHEMA using TLIRP grafting from approach was suggested by TGA analysis. It is anticipated that this facile strategy would uncover a cascade of novel fascinating materials for multifarious applications in material science and nanotechnology.
저자 Long Giang Bach, Md. Rafiqul Islam, 임권택
소속 부경대
키워드 Chemisorption; Nanocomposites; Controlled Radical Polymerization; PHEMA; SiO2 nanoparticles; TLIRP
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