| 학회 | 한국공업화학회 |
| 학술대회 | 2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 | 18권 1호 |
| 발표분야 | 포스터-정보.전자소재 |
| 제목 | Synthesis and Photovoltaic studies of New Semiconducting Copolymers for Bulk Heterojunction Polymer Solar Cells |
| 초록 | Donor–acceptor conjugated copolymers based on benzothiadiazole(BT), and carbazole(Cz) functional units were investigated for high-performance low bandgap polymer solar cells. A monomer consisting of benzothiadiazole as an electron-withdrawing group and carbazole as a spacer backbone was designed and the energy level was modulated by introducing suitable donor units. The synthesized monomers were polymerized by typical Suzuki-coupling reactions. Their chemical structures were confirmed by 1H-NMR, 13C-NMR and Gel permeation chromatography (GPC). Also, the electrochemical properties were estimated from UV-vis spectroscopy, cyclic voltammetry(CV), and photoluminescence(PL). The polymer solar cell devices were fabricated by solution processing and their photovoltaic properties were investigated by IPCE and PCE. |
| 저자 | 나윤정, 황석호 |
| 소속 | 단국대 |
| 키워드 | solar cell; Benzothiadiazole; Carbazole; Suzuki-coupling |
