초록 |
Excess molar enthalpies, HE, of binary mixtures of 2-Alkanol with n-Alkane have been measured at 313.15 K under atmospheric pressure using an isothermal microcalorimeter. The experimental HE values are positive for all the binary mixtures over the entire range of compositions. The experimental data have been correlated with the modified Redlich-Kister equation with 5 coefficients. And data also have been correlated with NLF-HB EoS (nonrandom lattice fluid equation of state with hydrogen bonding). |