화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터)
권호 22권 2호, p.2437
발표분야 촉매 및 반응공학
제목 Partial Oxidation of Methane to Methanol with CO2 over Metal Modified Zeolite Catalysts
초록 One of the technologies that are gaining prominence is the utilization of CO2 as an oxidant for catalytic transformations. Most of the oxidative transformation requires reductants when oxygen is used as an oxidant, however molecular oxygen, gives rise to combustion of hydrocarbons (especially at high quantities) and thus may not be particularly effective for improving selectivity. In the case of methane conversions into oxygenates such as methanol and acetic acid, simultaneous activation of C-H bond of methane and oxidant are required which have been known as very tough challenge due to the thermodynamic unfavorability. In this study we have successfully illustrated the possibility of formation of methanol using CO2 under concurrent feeding with methane in the continuous flow fixed-bed reactor over Cu loaded zeolite catalysts
저자 서동우, Ranjit, Abdelrahaman Rabie, 박상언
소속 인하대
키워드 비균질촉매
E-Mail
원문파일 초록 보기