| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.2273 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
A comparison of zeolite Ti-MWW, Ti-MCM-36 and TS-1 for liquid phase epoxidation of linear alkenes |
| 초록 |
Ti-MWW has been prepared by an acid treatment on a boron and titanium-containing lamellar precursor, which is hydrothermally synthesized using piperidine(PI) as a structure-directing agent. Ti-MCM-36 has also been synthesized via swelling and pillaring process using the same lamellar precursor. Ti-MWW, Ti-MCM-36 and TS-1 catalysts have been studied for the epoxidation of alkenes using hydrogen peroxide as an oxidant. Both Ti-MWW and Ti-MCM-36 showed superior activities to TS-1. This result is believed to be a consequence of differences on structures between them; supercages and the exterior 12-membered ring(MR) pockets of MWW structure and 12-MR pockets of high external surface area, which formed mesopore of MCM-36 materials. |
| 저자 |
이규용, 안화승
|
| 소속 |
인하대 |
| 키워드 |
Ti-MWW; Ti-MCM-36; epoxidation; alkene
|
| E-Mail |
|
| 원문파일 |
초록 보기 |
