화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 분자전자 부문위원회
제목 Effects of Dielectric Surface Properties on Crystal Structures and Electrical Properties of Organic Semiconductors
초록 There have been many efforts to achieve high-performance organic field-effect transistors (OFETs). One of the key controlling factors is to introduce physicochemically stable and organic-compatible dielectric surfaces, where organic semiconductors tend to grow into highly conjugated active layers. Here, polystyrene (PS)-grafted SiO2 hybrid layers were used as gate dielectrics for TES-ADT based OFETs. Dielectric roughness was controlled by grafting end-functionalized polystyrenes (PSs) to UVO3-treated SiO2 dielectrics. The polymer grafting densities could induce discernible surface roughnesses ranging from 0.2 nm to 1.5 nm. Changes in TES-ADT film microstructure were correlated to changes in the hole mobility of OFETs fabricated on these dielectrics. The primary impact of increased roughness was a decrease in the lateral size of crystal domains. These results confirmed that dielectric roughness is an important technical specification in flexible circuit design and fabrication.
저자 이슬이, 장미, 양회창
소속 인하대
키워드 dielectric; TESADT; interfacial engineering
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