| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 | 30권 2호 |
| 발표분야 | 고분자 합성 |
| 제목 | The Comparison of The Monomer Reactivity Ratio of Poly(VDF/TrFE)synthesized by Initiator Di Tert-Butyl Peroxide and 3,5,6-trichloroperfluorohexanoyl peroxide. |
| 초록 | Copolymers of vinylidene fluoride(VDF) and trifluoroethylene(TrFE) with the whole range of copolymer composition were synthesized by the radical polymerization method using a di-tert butyl peroxide as initiator. We obtained the monomer reactivity ratio and monomer-polymer composition diagram of VDF-TrFE using the Fineman and Ross method. The comparison of the monomer reactivity ratio between two initiators of di-tert butyl peroxide and 3,5,6-Trichloroperfluoro hexanoyl peroxide has been done. Fig. 1. Plot of (F/f)(f-1) vs, F2/f Fig. 2. Monomer- Polymer composition for VDF-TrFE diagram copolymer diagram of VDF-TrFE system. ization with least squares straight line. Reference 1. T. C. Chung, A. Petchsuk, Macromolecules , 35, 7678(2002). 2. Toshiharu YAGI and Masayoshi TATEMOTO, Polymer Journal, 11(6), 429(1979). 3. M. Fineman and S. D. Ross, Journal of Polymer Science, 5, 259(1950). |
| 저자 | 이상구1, 김광한1, 소원욱1, 박인준1, 이수복1, 이종대2 |
| 소속 | 1한국화학(연), 2충북대 |
| 키워드 | Vinylidene Fluoride-Trifluoroethylene Copolymer; Monomer Reactivity Ratio |
