초록 |
This talk deals with controlled polymerization and self-assembly of poly(arylene ether)s. Well-defined polymers based on poly(arylene ether sulfone)s with various compositions and architectures including rod-coil star-shaped block copolymers, core-functionalized multi-arm polymers, and sulfonated anionic random copolymers, were synthesized via chain-growth condensation polymerization (SNAr) and/or atom transfer radical polymerization. Architectural variation of polymers was attempted to produce unimolecular micelles, supramolecular fibers, and anionic surfactants. |