화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX)
권호 15권 2호, p.2017
발표분야 열역학
제목 Phase Equilibrium Calculations of CO2-IL System Using Cubic EoS and GC NLF-HB EoS
초록 Having negligible vapor pressures and the ability to dissolve both organic and inorganic substances, room temperature ionic liquid(RTIL)s are actively studied as a leading candidate to replace many of the organic solvents used in present industries. Because almost endless combinations of cations and anions are possible, a model which can predict the behavior of an IL from its structure is appreciated.
In this work, the phase equilibrium behavior of a number of carbon dioxide +IL systems is examined. The solubility data of carbon dioxide in differentILs are correlated using two equations of state Peng-Robinson, and group contribution hydrogen bonding non-random lattice fluid (GC NLF-HB) EoS. The calculated results are compared to evaluate the ability of the NLF-HB EoS as a model to describe the phase equilibrium of CO2+IL systems.
저자 김지은, 강정원
소속 고려대
키워드 NLF-HB EoS; ionic liquid; CO2 solubility; Cubic EoS
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