화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 가을 (10/24 ~ 10/26, 부산 BEXCO)
권호 18권 2호, p.2118
발표분야 열역학
제목 Physicochemical investigation of 1-hexyl-3-methylimidazoilium bis (trifluromethylsulfonyl) imide [hmim][Tf2N] + N-methyldiethanolamine (MDEA) binary mixtures at T= 303.15, 313.15 and 323.15 K
초록 Ionic liquids and aqueous amine are well known solvents for post combustion CO2 capture and natural gas processing. Therefore, a significant amount of work has been carried out regarding the investigation of their physicochemical properties. Hence, in this work, physicochemical properties such as densities and dynamic viscosity for 1-butyl-3-methylimidazoilium bis (trifluromethylsulfonyl) imide + N-methyldiethanolamine (MDEA) binary mixture have been measured as functions of composition at T= 303.15, 313.15 and 323.15K and atmospheric pressure. The observed data has been utilized to evaluate the excess molar volume, V12E and were fitted to Redlich-Kister polynomial equation to predict adjustable parameters along with standard deviations. This binary mixture exhibits a temperature-dependent behavior and densities decreased linearly with temperature. Excess molar volume showed positive deviation.
저자 Satish Kumar, 문 일
소속 연세대
키워드 MDEA; [hmim][Tf2N]; Excess volume; Redlich-Kister
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