화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 포스터-에너지저장·변환
제목 Functional interlayers comprising porous nanofibers with core–shell metal oxide@graphitic carbon nanoparticles and well grafted N-doped CNTs for excellent Li–S batteries​
초록 Rationally designed functional interlayers comprising hierarchically porous nanofibers embedded with core–shell Co3O4@graphitic carbon nanoparticles and well grafted N-doped carbon nanotubes (Co3O4@GC/N-CNTNF)​ for outstanding Li–S batteries. The highly conductive GC layer coated on Co3Onanoparticles along with the well-grafted N-doped CNTs provided numerous conductive channels for rapid charge transfer during the redox process. The Co3O4 nanoparticles functioned as active polar sites for effective capturing of polysulfides. Consequently,the assembled Li–S cell employing functional interlayer and a sulfur electrode(70 wt.% and 2.0 mg cm-2 loading) presented an excellent electrochemical performance, namely a high-rate capability and stable cycling performance at C-rates of 0.1, 0.5, and 1.0 C.



저자 rakesh saroha, 조중상
소속 충북대
키워드 Coated separators; N-doped carbon nanotubes; Cobalt oxides; Li–S batteries
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