| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Reversible phase transition of Poly(oxyethylene-b-butylene adipate) ionomers (POBA-is) induced by draw ratio |
| 초록 |
Shape memory polymers (SMPs) have widely been researched as smart materials which are capable of fixed a temporary shape and recovered to its original shape during stress-induced at near transition temperature. The fabrication of SMP synthesizes one or more oligomers to form a block copolymer. A series of segmented poly (oxyethylene-b-butylene adipate) ionomers (POBA-is) were prepared by two step polymerization of adipic acid, 1,4-butanediol and sodium sulfonateside chain-grafted poly-(ethylene oxide) (SPEO) with soft segment and ionic group. The chemical composition of these POBA-is were ascertained by 1H-NMRspectroscopy. We investigated the stress-induced phase transition in the process of the shape deformation and recovery using the wide angle X-ray analysis (WAXD). |
| 저자 |
이청일, 전상수, 임승순
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| 소속 |
한양대 |
| 키워드 |
Poly(oxyethylene-b-butylene adipate) ionomers (POBA-is); Reversible phase transition
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| E-Mail |
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