화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 From Basics to Applications for Polymer Industry (영어발표)
제목 Preparation and Characterization of Clay/Hydrogel Composites by Various Radical Polymerization
초록 The hydrogel was prepared with imogolite, halloysite, and laponite whose surface was activated by γ-ray irradiation to initiate gelation. The dynamic behavior of imogolite-poly(acrylic acid) nanocomposite hydrogels was investigated by dynamic light scattering (DLS), small angle X-ray scattering (SAXS) and small angle neutron scattering (SANS) to determine the effects of particle concentration and the magnitude of deformation. These measurements revealed that the imogolite network was composed of particle-overlaps. We also discuss the formation and structure of poly(n-isopropylacrylamide)-laponite hydrogel by γ-ray irradiation. γ-ray generates radicals and forms 3D networks without any cross-linker. The existence of clay cross-linker affects swelling abilities of hydrogels. The structure of swollen poly(n-isopropylacrylamide)-laponite hydrogel by γ-ray irradiation is also investigated and compared with other chemical methods.
저자 손대원
소속 한양대
키워드 hydrogel; radical polymerization; gamma irradiation
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