| 학회 |
한국고분자학회 |
| 학술대회 |
2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터) |
| 권호 |
42권 2호 |
| 발표분야 |
분자전자 부문위원회 I |
| 제목 |
Side Chain Engineering of NDI-based Polymers for Enhancing Electron Mobility |
| 초록 |
Recently, significant progress has been made in all polymer solar cells (all-PSCs) by modifying chemical structure and optimized architecture. Especially, close stacking of conjugated polymer has been an important issue for achieving efficient conducting pathways and charge transport property in bulk-heterojunction. Herein, a series of NDI-based polymers with controlled alkyl side chain was synthesized by Stille coupling reaction and investigated. At the optimized side chain of NDI-based polymers, UV-Vis spectra showed distinct shoulder peak and π-π stacking distance decreased. Consequently, electron mobility was increased up to 0.59, which is over 20 times that of NDI-based polymer with conventional branching point. |
| 저자 |
유호선1, 김동욱1, 조한희1, 김선주2, 김범준1
|
| 소속 |
1KAIST, 2CAU |
| 키워드 |
conjugated polymer; electron mobility; alkyl chain
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| E-Mail |
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