학회 |
한국공업화학회 |
학술대회 |
2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
권호 |
26권 1호 |
발표분야 |
포스터-에너지저장·변환 |
제목 |
Surface modification of carbon nanofibers using ferrocene for pseudocapacitor electrodes |
초록 |
Carbon/transition metal composites are promising materials for supercapacitors since carbon provides high surface area and conductivity while transition metal enables pseudocapacitance performance. Ferrocene-attached carbon nanofibers (CNFs) were prepared for supercapacitor electrdoes. CNFs were fabricated by thermal treatment of electrospun polyacrylonitrile (PAN). CNFs were activated using steam to functionalize their surface, and then ferrocenecarboxaldehyde was attached through covalent bonding. Electrochemical properties were studied using three-electode cells with Ag/AgCl as a reference electrode and Pt as a counter electrode. Fe/CNFs showed high capacitance of 358 F/g and energy density of 49.7 Wh/kg at 0.5 A/g, which is significantly higher that CNFs without the surface treatment (68 F/g and 9.4 Wh/kg). |
저자 |
정경혜, 김승아, 박경민
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소속 |
대구가톨릭대 |
키워드 |
carbon nanofibers; ferrocene; supercapacitors; pseudocapacitors
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E-Mail |
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