| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Synthesis of poly(oligoethyleneglycol methacrylate) coating TiO2 nanoparticles by surface-initiated ARGET ATRP |
| 초록 |
Poly(oligoethyleneglycol methacrylate) (POEGMA) covalently attached to TiO2 nanoparticles (NPs) were synthesized by the surface-initiated ARGET ATRP. The growth of polymer chains from the ATRP-initiator functionalized nanoparticles surface was achieved under mild condition by using copper (II) as a catalyst and zerovalent copper (Cu0) or L-ascorbic acid (AsAc) as reducing agents. The as-synthesized nanocomposites were characterized by FT-IR, TGA, FE-SEM and TEM analyses. FT-IR results suggested the formation of polymer chains covalently attached to nanoparticles surface. The TiO2 nanoparticles were found to be imbedded in polymer matrices as revealed by TEM and FE-SEM images. The TGA curves demonstrated that the using of AsAc afforded the faster grafting rate over Cu0. |
| 저자 |
김용훈, 임권택, Thanh Binh Mai, Thi Nga Tran, 김동우
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| 소속 |
부경대 |
| 키워드 |
TiO2 nanoparticles; ARGET ATRP; POEGMA-g-TiO2; surface-initiated polymerization; nanocomposites |
| E-Mail |
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