| 학회 | 한국공업화학회 |
| 학술대회 | 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 22권 2호 |
| 발표분야 | (특별세션) 에너지-화학 융복합 차세대기술의 현황 및 전망 |
| 제목 | CO2 수소화 포름산 촉매공정: KIST-KU formic acid process |
| 초록 | In this presentation, we report that simple ruthenium chloride treated bipyridine-incorporated covalent triazine framework efficiently catalyzes the hydrogenation of CO2 to formate with an unprecedented turnover frequency of 38,800 h−1. The catalyst, [bpy-CTF-RuCl3], demonstrated excellent recyclability over consecutive runs and produced a maximum final formate concentration of ~ 2.1 M in 3 h. In addition to this outstanding efficiency, the use of a simple, cheap, and commonly available metal precursor makes [bpy-CTF-RuCl3] attractive for its application as a green and practical catalyst for CO2 hydrogenation to formate. Based on this developed catalysts, KIST-KU process will be announced in this session. |
| 저자 | 정광덕1, 윤성호2 |
| 소속 | 1한국과학기술(연), 2국민대 |
| 키워드 | CO2 hydrogenation; formic acid; triethylamine |
