화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 고분자_포스터
제목 Clustered Si nanoparticles Yolk-shell structure by Organic/Inorganic hybrid polymerization for Li ion batteries
초록 Si anode has lots of problems such as volume expansion and poor electrical contact. For solving these problems, Yolk-shell structure is introduced and it shows good cycle stability and electrical conductivity. But Void engineered yolk-shell structure is suffered from very low initial coulombic efficiency because of high surface area. In this work, we propose a Si-clustered yolk-shell structure using hybrid polymerization. Si-clustered yolk-shell structure can get low surface area and exhibited higher initial coulombic efficiency about 80% and good cycle stability. By balancing the Si amount inside the shell, we could get optimal point showing high initial coulombic efficiency maintaining stable cycle stability.
저자 김태진, 유필진
소속 성균관대
키워드 Si; initial coulombic efficiency; Yolk-shell; hybrid polymerization
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