화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 촉매_포스터
제목 Synthesis of MgCl2-supported Ziegler-Natta catalyst and its evaluation in ethylene/1-octene polymerization
초록 The development of Ziegler-Natta catalyst has been the subject of active research for many years. It was discovered that highly active polymerization of ethylene is based on this type of  catalyst supported on activated MgCl2. There are different routes for the preparation of  MgCl2-supported catalyst. One of which is the chemical route, where active MgCl2 is generated and Ti compound and Lewis base are incorporated. In this study, supported catalyst with active MgCl2 were synthesize through the conversion of organomagnesium precursor to MgCl2 using chlorine-containing organoaluminum compounds. The synthesized Ziegler-Natta catalysts were used in ethylene-octene copolymerization at different temperatures. The effect of this activation process on the catalyst performance was investigated.
저자 Carino Ann Charise, 장푸른솔, 최우영, 고영수
소속 공주대
키워드 polyethylene; copolymerization; Ziegler-Natta catalyst
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