화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.712
발표분야 에너지/환경
제목 Optimized Hydrothermal Synthesis of LiFePO4-C Composites for Rechargeable Lithium Batteries
초록 LiFePO4-C composites were synthesized by a hydrothermal method and subsequent high-energy ball-milling. Different carbon conductive additives including nano-sized acetylene black and multi-walled carbon nanotube (MWCNT) were used to enhance the electronic conductivity of LiFePO4. The structural and morphological performance of LiFePO4-C composites was investigated by X-ray diffraction (XRD) and scanning electron microscopy. The electrochemical properties of Li/LiFePO4-C batteries were analyzed by cyclic voltammetry and charge/discharge tests. XRD results demonstrate that LiFePO4-C composites have an orthorhombic olivine-type structure with a space group of Pnma. Li/LiFePO4-C battery with 5 wt.% MWCNT displays the best electrochemical properties with a discharge capacity of 142 mAh g-1 at 0.25 C at room temperature.
저자 김 파1, 김은미2, 박경희3, 구할본1
소속 1전남대, 2Jilin Univ., 3China
키워드 Hydrothermal reaction; Ball-milling; Carbon conductive additives
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