화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 [촉매] 촉매화학적인 수소 생산기술 및 최신 동향
제목 Water electrolysis catalysts applied for membrane-electrode assembly
초록 Much efforts have been devoted to developing electrocatalystsapplicable to water electrolyzer. Among many candidates for oxygen evolution reaction (OER), NiFe layered doublehydroxide (LDH)-based electrocatalysts show the highest activity in an alkaline medium.Unfortunately, the poor electrical conductivity of NiFe-LDH limits itspotential as an electrocatalyst, which was often solved by hybridization withconductive carbonaceous materials. However, we find that using carbonaceousmaterials for anode has detrimental effects on the stability of AEMWE at industriallyrelevant current densities. In this work, a facile monolayer structuring issuggested to overcome low electrical conductivity and improve mass transportwithout using carbonaceous materials. The monolayer NiFe-LDH deposited on Nifoam showed much better AEMWE performance than conventional bulk NiFe-LDH, dueto better electrical conductivity and higher hydrophilicity.
저자 이현주, 전순서
소속 한국과학기술원
키워드 water; electrolysis; hydrogen; MEA
E-Mail