화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2005년 봄 (04/22 ~ 04/23, 여수대학교)
권호 11권 1호, p.695
발표분야 열역학
제목 High Pressure-Phase Equilibria of Binary Mixture ; Propane and HFC-227ea
초록 Basically, VLE data were used to design refrigerant cycle, therefore these data is requisite as a basic thermodynamic data. In this work, vapor-liquid equilibria were measured for binary mixture of propane + HFC-227ea within 273.15K to 313.15K in a circulation type equilibrium apparatus. The experimental data were calculated by PR(Peng-Robinson)EOS used Wong-Sandler mixing rules with combine NRTL excess Gibbs free energy model, PRSV(Peng-Rovinson-De Sants) EOS used Huron-Vidal mixing rules with combine NRTL excess Gibbs free energy model and CSD(Canahan-Starling-De Sants) EOS. Almost all the calculated values with this model give a good agreement with the experimental data and this system exhibit azeotropes.
저자 노희국1, 박지영2, 이병권3, 유기풍1, 임종성1
소속 1서강대, 2노스캐롤라이나 대, 3한국과학기술(연)
키워드 Phase equilibria; HFC-227ea; Propane; azeotropes
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