| 초록 |
Recently, 25 porphyrin based on coordination polymers were synthesized and characterized. Even if they have porosity, their adsorption properties were not studied except PPF-1. Here, we report CO2 and CO adsorption ability of the coordination polymer PPFs (Porphyrin Paddlewheel Frameworks) which were synthesized by solvothermal reaction of various metal salts, pillar linkers (pyrazine and 4,4-bipyridine), and TCPP (meso-Tetra(4-carboxyphenyl)porphine). H2 and N2 adsorption abilities of PPFs have already been reported. However, there is no data about CO2 and CO adsorption of PPFs. Therefore, we report CO2 and CO adsorption ability of PPFs. |
