화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자가공/복합재료-자가치유 고분자와 복합소재
제목 Novel stearic acid/graphene core-shell composite microcapsule as a phase change material exhibiting high shape stability and performance
초록 A stearic acid (SA)/graphene composite microcapsule, having a core-shell structure, is prepared for the first time using a latex technology for use as a novel composite phase change material (PCM) for thermal energy management. Melted SA is dispersed in water using an anionic surfactant as a stabilizer and cooled to prepare a water-based latex containing negatively charged SA particles. A simple mixing of this latex with an aqueous dispersion of graphene, prepared with aid of a cationic surfactant, results in the self-assembly of graphene on a SA particle surface by an electrostatic interaction, allowing for the encapsulation of SA with graphene to form a core-shell composite microcapsule. The protective graphene shell gives an excellent shape stability to the composite during phase change and a substantial improvement in thermal stability of the active SA core.
저자 다오, 간수크, 정한모
소속 울산대
키워드 Graphene; Nano composites; Core-Shell
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