학회 |
한국고분자학회 |
학술대회 |
2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전)) |
권호 |
33권 1호 |
발표분야 |
고분자 구조 및 물성 |
제목 |
Core-Shell type nanorods prepared from polymer bilayer using AAO template |
초록 |
In this study, we fabricated hexagonally packed core-shell nanorods consisting of poly(methyl methacrylate) (PMMA) as a core and polystyrene (PS) as a shell by sequential wetting of bilayer PS/PMMA film inside anodized aluminum oxide (AAO) template. We found that a reactive bilayer consisting of PMMA with epoxy functional group and PS with carboxylic acid functional group is necessary to form well-defined core-shell nanorods. On the contrary, nonreactive bilayer without having functional groups could not generate the core-shell structure due to their non-spontaneous spreading (negative spreading coefficient). The sizes of the core and the shell were easily controlled by adjusting the thickness of each layer. Acknowledgement: This work was supported by Creative Research Initiative Program supported by KOSEF |
저자 |
변진석, 이동현, 김진곤
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소속 |
포항공과대 |
키워드 |
core-shell; nanorods; bilayer; AAO
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E-Mail |
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