| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2039 |
| 발표분야 | 환경 |
| 제목 | Study the electrochemical redox behavior of Co2+ in PF-6, CF3SO3-, (CF3SO2)2-and BF-4 anion containing RTILs |
| 초록 | Difference in cell potential depending upon the anionic moiety in similar cation such as BMIM PF-6(4V), BMIMCF3SO3- (5V), BMIM (CF3SO2)-2(6V) and BMIMBF-4 (4V) makes initiate this work. Effect of anions in RTIL on the electrochemical redox properties of cation mediators was investigated. The following cyclic voltammogram demonstrates redox behavior of Co2+/Co3+ varied with various anionic groups containing IL. At first sight, the Co2+/Co3+ redox potential found at 1.4V, 1.8 and 2 V for CF3SO3- , (CF3SO2)-2, and PF-6 anions in IL respectively. Key words: RTIL, PF-6, CF3SO3-, (CF3SO2)-2 and BF-4, electrochemical studies, CoCl2. |
| 저자 | Kannan Karunakaran, 문일식 |
| 소속 | 순천대 |
| 키워드 | 친환경; 고효율; 친환경 공정 |
| 원문파일 | 초록 보기 |
