화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 고분자구조 및 물성
제목 Programmable Digital Memory Behaviors of Functional Aromatic Polyimides Bearing Triphenylamine Derivatives: Effects of Electron Donor and Acceptor Substituents
초록 A series of aromatic polyimides (PIs) were synthesized via the polymerization of 3,3′,4,4′-diphenylsulfonyltetracarboxylic dianhydride with 4,4′-diaminotriphenylamine derivatives containing hydrogen, cyano, methoxy, or dimethylamine substituents. Nanoscale thin films of the PIs demonstrated excellent electrical memory performance, with high stabilities and ON/OFF current ratios. The memory characteristics were found to be tunable by varying the substituents; nonvolatile WORM behavior, nonvolatile ON/OFF switching type memory behavior, and volatile DRAM behavior were observed. In addition, the film density was a significant factor influencing the observed memory behaviors. All of the memory behaviors were found to be governed by a mechanism involving trap-limited spacecharge-limited conduction and local filament formation.
저자 고용기1, 권원상1, Hung-Ju Yen2, Cha-Wen Chang2, 김동민1, 김경태1, 함석규1, 이택준1, Guey-Sheng Liou2, 이문호1
소속 1포항공과대, 2National Taiwan Univ.
키워드 Polymer memory; Non volatile memory; Polymer thin film
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