학회 |
한국고분자학회 |
학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
권호 |
37권 2호 |
발표분야 |
고분자구조 및 물성 |
제목 |
Programmable Digital Memory Behaviors of Functional Aromatic Polyimides Bearing Triphenylamine Derivatives: Effects of Electron Donor and Acceptor Substituents |
초록 |
A series of aromatic polyimides (PIs) were synthesized via the polymerization of 3,3′,4,4′-diphenylsulfonyltetracarboxylic dianhydride with 4,4′-diaminotriphenylamine derivatives containing hydrogen, cyano, methoxy, or dimethylamine substituents. Nanoscale thin films of the PIs demonstrated excellent electrical memory performance, with high stabilities and ON/OFF current ratios. The memory characteristics were found to be tunable by varying the substituents; nonvolatile WORM behavior, nonvolatile ON/OFF switching type memory behavior, and volatile DRAM behavior were observed. In addition, the film density was a significant factor influencing the observed memory behaviors. All of the memory behaviors were found to be governed by a mechanism involving trap-limited spacecharge-limited conduction and local filament formation. |
저자 |
고용기1, 권원상1, Hung-Ju Yen2, Cha-Wen Chang2, 김동민1, 김경태1, 함석규1, 이택준1, Guey-Sheng Liou2, 이문호1
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소속 |
1포항공과대, 2National Taiwan Univ. |
키워드 |
Polymer memory; Non volatile memory; Polymer thin film
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E-Mail |
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