| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Preparation of iron oxide nanoparticlesstablilzed by block copolymers carrying phenylboronic acid group |
| 초록 |
Water-soluble block copolymers exhibiting glucose-sensitive phase behavior using poly(ethylene oxide)-based RAFT agent and vinyl type monomer containg boronic acid group via RAFT radical polymerization were synthesized. First, living anionic ring-opening of ethylene oxide was performed in mixture of benzene and dimethyl sulfoxide using n-butyllithium and tert-butoxide as the initiating system. PEO-based macroinitiator was synthesized by chain-end functionalization of polymeric alkoxide using 2-bromoisobutyryl bromide under the high vacuum. The ω-brominated macroinitiator was converted to the corresponding RAFT agent. A glucose responsive copolymer was prepared by RAFT polymerization of m-(methacryloylamido) phenyl boronic acid in DMSO at 70℃ for 48 hours. Using the resulting block copolymer, nano sized iron oxide particles were prepared in aqueous media. In this presentation, we will report the preliminary results. |
| 저자 |
최진희, 김태환, 김근석, 이상미, 김진흥, 김정안
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| 소속 |
경희대 |
| 키워드 |
PEO; RAFT; nanoparticle
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| E-Mail |
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