| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
정밀화학 |
| 제목 |
Nickel-Catalyzed Hydrogenolysis of Arenesulfonates Using Secondary Alkyl Grignard reagents |
| 초록 |
Neopentyl arenesulfonates react with secondary alkylmagnesium chlorides in the presence of dppfNiCl2 to produce the corresponding arenes via the reductive cleavage of carbon−sulfur bond. Highest yield is obtained by using three equivalents of Grignard reagent to a mixture of arenesulfonate and dppfNiCl2 in Et2O at room temperature. This reaction represents a novel method allowing the efficient hydrogenolysis of sulfur-containing groups in aromatic compounds. |
| 저자 |
김철배, 박광용
|
| 소속 |
중앙대 |
| 키워드 |
hydrogenolysis; arenesulfonates; homogeneous nickel catalyst; secondary alkyl Grignard reagents
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| E-Mail |
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