화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 에너지저장변환
제목 High-Voltage Electrolyte Design for High-Energy Battery Cathode
초록 Li-rich layered xLi2MnO3·(1−x)Li(Mn,Ni,Co)O2 cathode materials have received a considerable attention because of their high capacity of over 250 mAhg−1, on the high-voltage operation above 4.6 V and low cost. Its performance upon high-voltage operation however is limited, due to anodic instability of conventional electrolyte and the cathode-electrolyte interfacial instability. Our approach to overcome this problem is to design new electrolyte components with high anodic stability above 4.6 V and to stabilize high-voltage interface of Li-rich layered oxide cathode. In this presentation, we report the high-voltage performance improvement of Li-rich layered oxide cathode using high-voltage additives, and the studies of interfacial reaction and surface film formation mechanisms.
저자 PHAM QUANG HIEU1, 송승완2, 황의형1, 권영길2, 이정규3
소속 1Department of Chemical Engineering & Applied Chemistry, 2Chungnam National Univ., 3Leechem Co.
키워드 Lithium Batteries; High-Voltage Cathode; Additive
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