화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 가을 (10/26 ~ 10/27, 한국과학기술원)
권호 13권 2호, p.1677
발표분야 분리기술
제목 Measurement and Correlation of Vapor-Liquid Equilbrium for the Multi-component Systems with Epichlorohydrin
초록 In the various chemical engineering processes design, ECH (Epichlorohydrin) is famous for the synthesis polymer. ECH is known as principal material in the production of epoxy resins, synthetic epoxy resins, synthetic glycerin, epichlorohydin elastomers and surfactants. Separation process plays an important role of ECH production. ECH is normally separated from mixture, and selection of proper extraction solvent is important. VLE (Vapor-Liquid Equilibrium) data is essential for design and operation of separation processes. In this study, VLE phase compositions were measured for the binary system composed of ECH, toluene and benzene. To measure the solubility of this system, VLE measurement apparatus, a dynamic recirculating all-glass cell (Labodest model), was used and the compositions were analyzed by GC (Gas Chromatography). Measured VLE data were correlated by PR, SRK and NLF-HB (Nonrandom Lattice Fluid with Hydrogen Bonding) Equation of State.
저자 이용화, 강정원
소속 고려대
키워드 VLE; Epichlorohydrin; Vapor liquid Equilibrium; Equation of State; EOS
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