| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
고분자가공/복합재료-자가치유 고분자와 복합소재 |
| 제목 |
Functionalization of Cellulose Nanocrystal and Its Use as Reinforcement for Polylactide Nanocomposites |
| 초록 |
Cellulose nanocrystal (CNC) obtained by acid hydrolysis from microcrystalline cellulose contains many hydrophilic OH groups which decrease compatibility with polylactide. The effective functionalization of CNC is conducted to convert hydrophilic groups into alkyl group by nucleophilic substitution reaction and the degree of substitution is quantitatively determined. The polylactide nanocomposites reinforced by functionalized CNC were prepared by solution casting method and the effects of functionalized CNC on the thermal and rheological behavior, crystallinity, and mechanical properties have been investigated. The mechanical property modeling is also evaluated to simulate the moduli of the composites and compared with the experimental values. This study accounts for the effect of functionalized CNC on polylactide matrix, providing a design guide for eco-friendly nanocomposites in industrial fields. This research is supported by Korea Ministry of Environment. (Project No. 2013001470001) |
| 저자 |
박상호, 김성훈
|
| 소속 |
한양대 |
| 키워드 |
Cellulose nanocrystal; Polylactide
|
| E-Mail |
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