| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
Korea-Japan Joint Symposium: Assembly Technology in Polymer Science(초청-영어발표/포스터-국문발표 가능) |
| 제목 |
Tyrosine mediated 2D peptide assembly and its role as a bio-inspired catalytic scaffold |
| 초록 |
In two-dimensional interfacial assembly, interplay between molecular ordering and interface geometry determines the final morphology and local geometry. We present the spontaneous assembly of a designed peptide displaying facet formation of a water droplet. The identified peptides had a strong driving force to flatten the rounded top of hemispherical water droplet into a plane with a macroscopic 2D crystal structure. The facet formation phenomena is driven by interactions of tyrosine and cross-linked stabilization by cysteine. In this study, we revealed the crucial sequence motifs for facet formation and folding structures. The well-ordered redox active tyrosine in the 2D peptide film can enhance chemical/electrochemical reaction, and the assembled peptide film can potentially provide a platform to construct a molecularly tunable, self-repairable peptide or hybrid film. |
| 저자 |
Ki Tae Nam1, Yoon-Sik Lee2, Hyung-Seok Jang3, Jung-Ho Lee2, Yong-Sun Park3, Jimin Park2, Tae-Youl Yang1, Kyoungsuk Jin2, Jae Hun Lee1, Sunghak Park2, Jae Muoyng You1, Ki-Woong Jeong2, Areum Shin1, In-Seon Oh2, Min-Kyung Kwon1, Yong-Il Kim2, Hoon-Hwe Cho1, Heung Nam Han2, Yangmee Kim1, Yoon Ho Chang2, Seung R. Paik3
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| 소속 |
1Department of Materials Science and Engineering, 2Seoul National Univ., 3School of Chemical and Biological Engineering |
| 키워드 |
interfacial assembly; peptide film; catalytic scaffold
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| E-Mail |
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