| 초록 |
Hexafluoropropylene oxide(HFPO) has been used in preparation of perfluoropolyethers(PFPEs) as a high performance lubricants. HFPO was synthesised by oxidation methods using oxygen, hydrogen peroxide, and sodium hypochlorite solution. Especially, preparation method by oxidation of sodium hypochlorite (NaOCl) solution is the highest hexafluoropropylene(HFP) conversion. In this study, HFPO was synthesised by oxidation of HFP using NaOCl solution and trioctylmethylammonium chloride(TOMAC) as phase transfer catalyst(PTC). The conversion and identification of reaction for the preparation of HFPO were confirmed results by gas chromatography/mass spectrometry(GC/MS). |
