화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 합성
제목 Synthesis and Characterization of Photovoltaic Polymers Containing both Tetrathiafulvalene and Fullerene
초록 A photovoltaic polymer containing both tetrathiafulvalene and fullerene was successfully synthesized via coupling reactions. The synthesized molecule was abbreviated as T6F12, where 6 and 12 mean the numbers of sulfur in mesogen and carbons in alkyl chains, respectively, and T and F represent tetrathiafulvalene and fullerene, respectively. Electron-rich tetrathiafulvalene (T) can work as an electron donor (D) and fullerene (F, C60) can act as an electron acceptor (A) so that the chemical architecture of T6F12 is a D-A dyads system. The chemical structure of T6F12 was confirmed by utilizing FT-IR, 1H and 13C NMR, and its thermal behavior was monitored by DSC.
저자 이세현, 국윤배, 정광운, 이명훈, 왕뢰, 김영곤
소속 전북대
키워드 photovoltaic polymer; tetrathiafulvalene; fullerene; electron donor; electron acceptor
E-Mail