화학공학소재연구정보센터
학회 한국재료학회
학술대회 2008년 가을 (11/07 ~ 11/07, 차세대융합기술연구원)
권호 14권 2호
발표분야 전자재료
제목 Growth of Double- or Triple-Walled Carbon Nanotube Arrays via Block Copolymer Lithography
초록 We demonstrate a highly efficient and size selective growth of nitrogen doped CNTs combining a plasma-enhanced CVD (PECVD) process with block copolymer lithography. Self-assembled block copolymer templates provided hexagonal nanoporous PS templates and tilted evaporation of iron over the nanoporous template and thermal treatment generated a hexagonal array of catalyst particles with a sub-nanometer scale tunability of their size. Nitrogen-doped CNT array was grown from the nanopatterned catalysts by a PECVD under an ammonia environment and a supergrowth CNT arrays was successfully grown by the investigation of various growth conditions. Our scalable process complemented by sub-nanometer scale engineering of catalyst particles attained a highly selective growth of double-walled and triple-walled nanotubes.
저자 이덕현, 김상욱, 이원종
소속 KAIST
키워드 Carbon nanotubes; Block copolymers; PECVD
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