화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 분자전자 부문위원회 I
제목 Mediator extraction treatment as a fast and simple process for preparation of perovskite films and photovoltaic applications
초록 Despite of a high efficiency of the perovskite solar cells (PSCs) over 22%, the large-area fabrication of PSCs toward commercialization will be another issue receiving growing attention. Due to their easier controllability of morphology and better reproducibility, two-step fabrication has been preferred to apply large-area coating via printing process, rather than one-step. The main obstacles for the traditional two-step process, however, was a slow and incomplete conversion of PbI2 to perovskite. Herein, we proposed a fast and simple process for preparation of a high quality perovskite film suitable for large-area fabrication and mass production. Mediator extraction treatment (MET) resulted in a morphological change in PbI2-DMSO complex film that is completely converted into MAPbI3 film via fast reaction with MAI within several minutes. This MET process was demonstrated in MAPbI3-based PSCs using a slot-die coating to show a comparable performance to that made using spin-coating.
저자 김영윤, 박은영, 양태열, 정의혁, 서장원
소속 한국화학(연)
키워드 Perovskite solar cells; large-area; two-step process
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