| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-에너지저장·변환 |
| 제목 | Electrodeposited Thin Li Metal Anodes Protected via Electroless In Plating For All-Solid-State Batteries |
| 초록 | Lithiummetal is a promising anode for next-generation all-solid-state Li metal batteries(ASLMBs) due to its high theoretical capacity (3,860 mA h g-1) and lowestelectrochemical potential (-3.04 V vs. SHE). Sulfide-based solid electrolytes(SEs) attract much attention thanks to their high ionic conductivities as high asthose of liquid electrolytes and deformable mechanical properties. However, ASLMBs using sulfide SEs suffer destructive electrochemical evolution owing to the unstableinterfaces between Li metal and SEs, which originates from i) the lowelectrochemical voltage windows of sulfide-based SEs and ii) the penetratinggrowth of Li metal via grain boundaries or defects of SEs. Herein, wereport on interfacial evolution between thin Li metal anodes and SEs for ASLMBs.The interfacial stability improved by the In/LixIn protective layerswill be presented along with operando electrochemical pressiometry analysisresults. |
| 저자 | 전승구, 임해찬나라, 정윤석 |
| 소속 | 연세대 |
| 키워드 | All-solid-state batteries; Li metal anode; Pressiometry |
