| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 | 30권 1호, p.336 |
| 발표분야 | 고분자 합성 |
| 제목 | Synthesis of Poly(ethyrene oxide) carry out specific functional group |
| 초록 | n-Butyllithium-initiated ring-opening polymerization of ethylene oxide in the presence of t-BuO-K+ was successfully carried out in the mixture of benzene and dimethylsulfoxide at 40℃ for 48h. This polymerization system provided the best method to control the molecular weight of the PEO formed. The resulting polymeric alkoxide retained the living nature resulting in the production of chain-end functionalized PEO by reacting with a variety of electrophiles such as 1,3-propane sultone, propylene sulfide, trimellitic anhydride chloride, or 2-bromopropyl bromide or 2-bromoisobutyryl bromide. the functionalization yields were over 97mol%. In this presentation, we will report the result for the chain-end functionalization of PEO. |
| 저자 | 이철한1, 김지희2, 곽순종1, 황승상1, 김광웅1, 김정안1 |
| 소속 | 1한국과학기술(연), 2율촌화학 |
| 키워드 | PEO; Living polymerization; fullerene |
