| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Design, Synthesis, and Applications of Shape-Persistence Metallomacrocycles |
| 초록 |
A series of metallomacrcycles employing functional bis(terpyridine) building blocks were designed and constructed by both self-assembly and step-wise procedures. Based on terpyridine-metal(II)-terpyridine connectivity, application oriented metallomacrocycles possessing controlled ligand juxtapositioning (i.e., 60°, 109°, 120° angles) led to the ability to form trigonal, pentagonal, and hexagonal shape-persistence metallomacrocycles, respectively. All the intermediates and final products were characterized by means of 1H NMR 13C NMR, UV/Vis, and mass techniques. Studies of their applications such as photoelectrochemical and luminescence properties have shown these metallomacrocycles to be useful for fabricating molecular devices such as dye-sensitized solar cells and OLED. |
| 저자 |
황석호1, 이상원2, 허완수2, 차희철1, George R. Newkome3
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| 소속 |
1한국생산기술(연), 2숭실대, 3Univ. of Akron |
| 키워드 |
Metallomacrocycle; bis(terpyridine); Transition metals; Shape-persistence
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| E-Mail |
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