학회 |
한국공업화학회 |
학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
권호 |
20권 1호 |
발표분야 |
환경에너지_포스터 |
제목 |
Development of tubular reactor and zeolite separator for effective generation of Co3+ |
초록 |
For minimization of working electrochemical cell area, cylindrical cell development is inevitable. Successful operation of divided cylindrical cell possible only by developing tubular stable separator, which will keep the anodic and cathodic compartments separated from each other for bringing out required anodic and cathodic reactions. Here zeolite coated ceramic tubular membrane was attempted in newly developed tubular cell assembly for its initial optimization through Co2+ oxidation. First, firm attachment of cylindrical membrane was confirmed by migration of Co2+ ions that was analyzed by UV-visible spectroscopy. Then, electrolysis was carried out in presence of Co2+ ions at anodic part in H2SO4 medium. The oxidation efficiency of Co2+ calculated by potentiometric titration and compared with the results of plate and frame type cell divided by Nafion membrane at 30 ºC. |
저자 |
G. MUTHURAMAN, A.G.Ramu, 문일식
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소속 |
순천대 |
키워드 |
Tubular divided electrochemical cell; cylindrical membrane; zeolite membrane; electrochemical oxidation
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E-Mail |
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