화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터)
권호 15권 1호
발표분야 촉매
제목 Pd-Pt/Al2O3 Bimetallic Catalysts for the Advanced Oxidation of Reactive Dye Solutions
초록 The Pd-Pt/Al2O3 bimetallic catalysts showed high activities toward the wet oxidation of the reactive dyes in the presence of 1% H2 together with excess oxygen. Palladium was believed to act as a promoter to spillover the adsorbed H2 onto the surface of the oxidized Pt surface, and thereby the reducibility of the Pt increased greatly. The organic dye molecule had higher chance to adsorb on the reduced Pt surface under the competition with excess oxygen, which is an essential step for the catalytic wet oxidation. The Pd-Pt/Al2O3 catalysts also produced H2O2 from H2/O2 mixture, and the hydroxyl radical was formed through the subsequent decomposition of H2O2.
저자 이동근, 이학봉, 이상준, 레넥투안, 장기, 소니아 헤남, 조미정
소속 경상대
키워드 Catalytic wet oxidation; Pd-Pt/Al2O3 bimetallic catalysts; reactive dye solutions; hydrogen peroxide; reducibility
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