| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
Alkynyl-Substituted D-π-A Structural Zn(II)-Porphyrin Sensitizers Containing Various Donor Units for Dye-Sensitized Solar Cells |
| 초록 |
Dye-sensitized solar cells(DSSCs) have been regarded as next-generation photovoltaics for providing electricity at lower expense and more versatility. Porphyrins are one of the most widely studied sensitizers for DSSCs because of their absorbing strong Soret bands and Q bands. New alkynyl-substituted porphyrin sensitizers were designed and synthesized with the combination of the bulky triphenylamine(TPA) derivatives as the donor, such as dihexyloxy-substituted TPA and bis(dihexyloxy)phenyl-substituted TPA moiety, double alkynyl-substituted porphyrin as the π-bridge and benzothiadiazole(BTD)-based derivative as the acceptor. Porphyrin with doubly alkynyl substituent was introduced as the π-bridge unit for red-shifting the Soret and Q bands with respect to single alkynyl-substituted porphyrin. In this study, their structure-performance relationships were investigated with the influence of the various donor moieties on the photophysical, electrochemical and photovoltaic properties. |
| 저자 |
강성호1, 김환규2, 정승영1
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| 소속 |
1Global GET-Future Lab. and Department of Advanced Materials Chemistry, 2Korea Univ. |
| 키워드 |
D-π-A structural Zn(II)-porphyrin sensitizer; dye-sensitized solar cells; structure-performance relationship
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| E-Mail |
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