| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
Effect of planar or electron-withdrawing unit in conjugated polymer for ambipolar organic thin-film transistors |
| 초록 |
Organic thin film transistors (OTFTs) based on conjugated polymers are gaining attention due to their potential in solution processability and flexibility on the plastic substrate. For high-performance materials in OTFTs, conjugated polymers usually have planar backbone structures and alternation of electron donor (D) /acceptor (A) unit which are beneficial to achieve extended π–electron system and strong intermolecular interactions. D-A combination allows to adjust energy levels to realize the ambipolar OTFT properties. Due to its coplanar fused rings and imine groups, thiazolothiazole (TTz) unit shows strong π-π stacking and electron accepting tendency. Thienylenevinylene (TV) also has good planarity and an extended π-conjugation system because of the presence of a vinylene spacer. In this study, we present synthesis of TTz-TV copolymer and other two comparable materials to check the variation of the planarity and the tendency of ambipolar charge transport behavior. |
| 저자 |
김동유, 강민지, 장수영, 임대희
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| 소속 |
광주과학기술원 |
| 키워드 |
Organic thin-film transistor; synthesis; planarity; ambipolar; thiazolothiazole; thienothiophene
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| E-Mail |
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