화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 나노_포스터
제목 Octahedral CeO2:Eu3+ nanocrystals: enhanced light harvesting of dye-sensitized solar cells via light-scattering and downconversion photoluminescence
초록 Single-crystalline, octahedral CeO2:Eu3+ nanocrystals is prepared using a simple hydrothermal method. The size of the CeO2:Eu3+ nanocrystals (300−400 nm), as well as their mirror-like facets, significantly improved the diffuse reflectance of visible light. Excitation of the CeO2:Eu3+ nanocrystal with 330 nm ultraviolet light was re-emitted via downconversion photoluminescence (PL) from 570 to 672 nm. Downconversion PL was dominant at 590 nm and had a maximum intensity for 1 mol % Eu3+. The CeO2:Eu3+ nanocrystal-based DSSCs exhibited a power conversion efficiency of 8.36%, an increase of 14%, compared with conventional DSSCs, because of the strong light-scattering and downconversion PL of the CeO2:Eu3+ nanocrystals.
저자 장정식, 노종민
소속 서울대
키워드 CeO2:Eu3+ nanocrystals; dye-sensitized solar cells; light-scattering; downconversion
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