화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 촉매_포스터
제목 Ordered Mesoporous Transition Metal Oxides : Energy Storage for Lithium-Sulfur Cathode
초록 Lithium–sulfur batteries are upcoming electrochemical devices due to its advantages such as high specific capacity and energy density. Despite its superiority, practical use of Li–S battery is impeded because of obstacles; insulating character of sulfur and dissolution of polysulfide Intermediates. Majority of studies have focused on porous carbon materials not only to impart sulfur conductivity but also to capture polysulfide by physisorption.
In this work, we present new possibility of porous metal oxides (MOx) for Li–S battery cathode as host material. We expect that our cathode can effectively trap polysulfide by chemisorption and retard the dissolution of it. Consequently, it results in better cycling performance. Ordered mesoporous MOx (TiO2, MnO, NiO) were synthesized by a nano-replication method via ordered mesoporous silica (KIT-6). The materials were characterized by X-ray diffraction, N2 adsorption/desorption,  scanning electron microscopy.
저자 최윤석, 오세민, 김지만
소속 성균관대
키워드 Lithium-Sulfur; Cathode; Mesoporous; Battery
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