| 학회 |
한국화학공학회 |
| 학술대회 |
2013년 가을 (10/23 ~ 10/25, 대구 EXCO) |
| 권호 |
19권 2호, p.1651 |
| 발표분야 |
에너지 |
| 제목 |
A study on vanadium crossover using pore filling membranes for vanadium redox flow batteries |
| 초록 |
Novel pore-filling membranes with low vanadium crossover were developed for the application to a vanadium redox flow battery. The polymer electrolytes consisting of the whole hydrocarbon materials were introduced into porous hydrocarbon substrates and crosslink-polymerized by radical polymerization in this work. The thickness of the prepared membranes was controlled between 20 and 25 micrometers to extremely lower membrane resistances. Finally, film-like polymer electrolyte membranes were prepared. The prepared pore-filling membranes are able to drastically decrease vanadium co-ion crossover through the membrane because the porous substrate suppresses a swelling factor of highly functionalized electrolytes in water media such as liquid phase operation conditions. The physico-chemical properties of the prepared membranes such as swelling behavior, membrane area resistance, vanadium co-ion crossover were investigated in correlation with the electrolyte composition. Also the thermal and the structural property of the prepared pore-filling membranes were evaluated. |
| 저자 |
이미순, 최영우, 신경희, 양태현
|
| 소속 |
한국에너지기술(연) |
| 키워드 |
VRB; pore filling membrane; crossover
|
| E-Mail |
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| 원문파일 |
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