| 학회 | 한국화학공학회 |
| 학술대회 | 2005년 가을 (10/21 ~ 10/22, 인하대학교) |
| 권호 | 11권 2호, p.2121 |
| 발표분야 | 에너지/환경 |
| 제목 | Destruction of Aniline by Mediated Electrochemical Oxidation Process using Ce(IV) in Nitric Acid – Lab. Scale Study |
| 초록 | Mediated electrochemical oxidation (MEO) has been employed for destruction of organic wastes. We report Ce(IV) – mediated electrochemical oxidation of aniline as an example of organic waste. Aniline was oxidized by Ce(IV) in liquid reactor and carbon dioxide was produced as a final oxidation product. With this purpose, we have developed a mini-scale MEO system. In batch-scale experiments, the kinetics of destruction of aniline by MEO process with Ce(IV) was measured. It is established that at temperature of 90℃ destruction of aniline was found to be more than 90%. The results obtained from the redox potential and moles of Ce(IV), testify in favor of the mechanism of destruction of aniline with multi-electron coefficient n=28 ([Ce(IV)]/[Aniline] = 28). |
| 저자 | 블라디미르 바브로프, 정상준, 문일식 |
| 소속 | 순천대 |
| 키워드 | MEO; Aniline; Destruction; Batch reactor; Flow reactor |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
