화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산))
권호 12권 1호
발표분야 고분자
제목 Preparation of organic-inorganic polyelectrolyte membrane using a novel sulfonated Polyhedral Oligomeric Silsesquioxanes (POSS) for Direct Methanol Fuel cell
초록 Nafion is in the spotlight at the fuel cell system because of excellent mechanical property, chemical property and high proton conductivity. However, in DMFC, Nafion shows high methanol crossover which cause low power density and cell efficiency. In this study, Nafion/sulfonated octaphenyl POSS (sPOSS) nanocomposite membranes were prepared by solution casting method with various contents of sPOSS to improve proton conductivity and also suppress methanol crossover. Proton conductivity and methanol permeability were evaluated to confirm the effect of sPOSS dispersed in Nafion membrane. Morphology and thermal stability were also characterized.
저자 양태욱, 배진우, 김진우, 조재영
소속 서울대
키워드 Nafion; POSS; DMFC; nanocomposite; methanol crossover
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