| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
대학원생 구두발표 |
| 제목 |
Hierarchical Structures in Thin Films of Polymethacrylate DiblockCopolymer grafted with POSS Moieties |
| 초록 |
The morphological structures in thin films of a diblock copolymer of methyl methacrylate and polyhedral oligomeric silsesquioxane (POSS) functionalized methacrylate (PMMA-b- PMAPOSS) with a volume ratio of 13/87 were investigated in detail by using synchrotron grazing incidence small and wide-angle X-ray scattering (GISAXS and GIWAXS). Thin films of this diblock copolymer were found to undergo phase-separation during solvent-annealing with carbon disulfide and post thermal annealing. The cylinders of PMMA blocks are induced to form in the diblock copolymer films by solvent-annealing and are hexagonally packed in the PMAPOSS matrix, in which the cylinders are oriented vertically with respect to the film plane. And post thermal annealing process induces aggregation of the POSS moieties, which results in the formation of crystals with an orthorhombic lattice unit cell. |
| 저자 |
안병철1, 진상우1, Hirai Tomoyasu2, 노예철1, 정성민1, 정정운1, 김경태1, 김미희1, 김동민1, 고용기1, 박삼대1, 김진철1, 권원상1, 최준만1, Gopalan Padma3, Hayakawa Teruaki2, 이문호1
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| 소속 |
1포항공과대, 2동경공대, 3위스콘신대 |
| 키워드 |
GIXS; GISAXS; GIWAXS; Block copolymer; Thin film; organic-inorganic hybrid
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| E-Mail |
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